A new iron(II) mixed sandwich featuring a hybrid η6- Zwitterionic/η5-Iminocyclohexadienyl structure

Walter Figueroa, MAURICIO DANIEL FUENTEALBA CARRASCO, Carolina Manzur, David Carrillo, Andrés I. Vega, Jean Yves Saillard, Jean René Hamon

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

The neutral air-sensitive Fe(II) hydrazonyl complex CpFe{(η-C 6H5)NN=CHC6H4-p-NMe2} (2) is obtained by deprotonation of its cationic hydrazone precursor [CpFe{(η6-C6H5)NHN=CHC6H 4-p-NMe2}]+PF6- (1) with t-BuOK in tetrahydrofuran. The spectroscopic data, the X-ray molecular structure, and a DFT MO analysis revealed that 2 is best described as a hybrid of η5-iminocyclohexadienyl and η6-zwitterionic complexes.

Original languageEnglish
Pages (from-to)2515-2518
Number of pages4
JournalOrganometallics
Volume23
Issue number11
DOIs
StatePublished - 24 May 2004

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