Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium(II) derived from 2-ferrocenyl-1,8-naphthyridine

C. Zúñiga; S. A. Moya; M. Fuentealba; B. Aranda; P. Aguirre

doi:10.1016/j.inoche.2011.03.043

Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium(II) derived from 2-ferrocenyl-1,8-naphthyridine

C. Zúñiga, S. A. Moya, M. Fuentealba, B. Aranda, P. Aguirre

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

2-Ferrocenyl-1,8-naphthyridine (1) and cis,cis,cis-dicarbonyl-dichloro-bis (2-ferrocenyl-1,8-naphthyridine) ruthenium(II) complex (2) have been synthesized and characterized by IR, ¹H-NMR spectroscopy and elemental analysis. The structure of the compounds was determined by X-ray analysis. The complex (2) showed catalytic activity in the hydrogenation reaction of N-benzylideneaniline by hydrogen transfer with conversions between 89% and 33% for catalyst/substrate relations 200/1 and 400/1.

Original language	English
Pages (from-to)	964-967
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2011.03.043
State	Published - Jun 2011
Externally published	Yes

Keywords

Catalysts ruthenium
Hydrogenation imine
Ruthenium complex

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10.1016/j.inoche.2011.03.043

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title = "Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium(II) derived from 2-ferrocenyl-1,8-naphthyridine",

abstract = "2-Ferrocenyl-1,8-naphthyridine (1) and cis,cis,cis-dicarbonyl-dichloro-bis (2-ferrocenyl-1,8-naphthyridine) ruthenium(II) complex (2) have been synthesized and characterized by IR, 1H-NMR spectroscopy and elemental analysis. The structure of the compounds was determined by X-ray analysis. The complex (2) showed catalytic activity in the hydrogenation reaction of N-benzylideneaniline by hydrogen transfer with conversions between 89% and 33% for catalyst/substrate relations 200/1 and 400/1.",

keywords = "Catalysts ruthenium, Hydrogenation imine, Ruthenium complex",

author = "C. Z{\'u}{\~n}iga and Moya, {S. A.} and M. Fuentealba and B. Aranda and P. Aguirre",

note = "Funding Information: The authors acknowledge the financial support of Fondecyt-Chile (Project 1085135 and Project 3090035 ). ",

year = "2011",

month = jun,

doi = "10.1016/j.inoche.2011.03.043",

language = "English",

volume = "14",

pages = "964--967",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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number = "6",

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TY - JOUR

T1 - Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium(II) derived from 2-ferrocenyl-1,8-naphthyridine

AU - Zúñiga, C.

AU - Moya, S. A.

AU - Fuentealba, M.

AU - Aranda, B.

AU - Aguirre, P.

N1 - Funding Information: The authors acknowledge the financial support of Fondecyt-Chile (Project 1085135 and Project 3090035 ).

PY - 2011/6

Y1 - 2011/6

N2 - 2-Ferrocenyl-1,8-naphthyridine (1) and cis,cis,cis-dicarbonyl-dichloro-bis (2-ferrocenyl-1,8-naphthyridine) ruthenium(II) complex (2) have been synthesized and characterized by IR, 1H-NMR spectroscopy and elemental analysis. The structure of the compounds was determined by X-ray analysis. The complex (2) showed catalytic activity in the hydrogenation reaction of N-benzylideneaniline by hydrogen transfer with conversions between 89% and 33% for catalyst/substrate relations 200/1 and 400/1.

AB - 2-Ferrocenyl-1,8-naphthyridine (1) and cis,cis,cis-dicarbonyl-dichloro-bis (2-ferrocenyl-1,8-naphthyridine) ruthenium(II) complex (2) have been synthesized and characterized by IR, 1H-NMR spectroscopy and elemental analysis. The structure of the compounds was determined by X-ray analysis. The complex (2) showed catalytic activity in the hydrogenation reaction of N-benzylideneaniline by hydrogen transfer with conversions between 89% and 33% for catalyst/substrate relations 200/1 and 400/1.

KW - Catalysts ruthenium

KW - Hydrogenation imine

KW - Ruthenium complex

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U2 - 10.1016/j.inoche.2011.03.043

DO - 10.1016/j.inoche.2011.03.043

M3 - Article

AN - SCOPUS:79955824107

SN - 1387-7003

VL - 14

SP - 964

EP - 967

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium(II) derived from 2-ferrocenyl-1,8-naphthyridine

Abstract

Keywords

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