TY - JOUR
T1 - Chlorobis[1,1′-diphenylhydrazido(2-)-N 2]-[hydridotris(pyrazolyl-N2)borato]molybdenum(VI)
AU - Manzur, Carolina
AU - Carrillo, David
AU - Boys, Daphne
PY - 1997/10/15
Y1 - 1997/10/15
N2 - The MoVI atom in the title complex, [MoCl(C9H10BN6)-(C12H 10N2)2] or TpMo(NNPh2)2Cl, where Tp = HB-(C3H3N2)3-, has a distorted octahedral environment afforded by the facially coordinated Tp ligand, two terminal NNPh2 ligands and the chloro ligand. The bond distances Mo-N of 1.773 (3) and 1.780 (3) Å, N-N of 1.319(4) and 1.312 (4) Å, and bond angles MoN-N of 167.1 (2) and 170.9(3)°, in the Mo(NNPh2)2 moiety, together with the absence of pyramidalization on the N atoms remote from the Mo atom, are indicative of an extensive delocalization of the π-electron density throughout the Mo-N-N system.
AB - The MoVI atom in the title complex, [MoCl(C9H10BN6)-(C12H 10N2)2] or TpMo(NNPh2)2Cl, where Tp = HB-(C3H3N2)3-, has a distorted octahedral environment afforded by the facially coordinated Tp ligand, two terminal NNPh2 ligands and the chloro ligand. The bond distances Mo-N of 1.773 (3) and 1.780 (3) Å, N-N of 1.319(4) and 1.312 (4) Å, and bond angles MoN-N of 167.1 (2) and 170.9(3)°, in the Mo(NNPh2)2 moiety, together with the absence of pyramidalization on the N atoms remote from the Mo atom, are indicative of an extensive delocalization of the π-electron density throughout the Mo-N-N system.
UR - http://www.scopus.com/inward/record.url?scp=0031246197&partnerID=8YFLogxK
U2 - 10.1107/S0108270197007452
DO - 10.1107/S0108270197007452
M3 - Article
AN - SCOPUS:0031246197
SN - 0108-2701
VL - 53
SP - 1401
EP - 1403
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 10
ER -