Convenient access to new mono- and dinuclear organometallic hydrazones from [(η5-Cp)Fe(η6-arylhydrazine)]+

Carolina Manzur, Lorena Millán, Mauricio Fuentealba, Jean René Hamon, David Carrillo

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13 Scopus citations

Abstract

New mononuclear and dinuclear organometallic hydrazones [(η5- Cp)Fe(η6-R-C6H4NHN=CR'R'')]+PF6-, were synthesised by reacting the corresponding organometallic hydrazines [(η5-Cp)Fe(η6- RC6H4NHNH2)]+PF6-, with acetone, R=H, 2-Cl, 4-Me, 4-MeO; R'=R''=Me, and formylferrocene, R=H, 4-Me; R'=H; R''=(η5-C5H4)FeCp, respectively. (C) 2000 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)3615-3617
Number of pages3
JournalTetrahedron Letters
Volume41
Issue number19
DOIs
StatePublished - 6 May 2000
Externally publishedYes

Keywords

  • Aromatic spacer
  • Ferrocenyl complexes
  • Homodinuclear complexes
  • Iron sandwich
  • Organometallic hydrazines
  • Organometallic hydrazones

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