Convenient access to new mono- and dinuclear organometallic hydrazones from [(η 5 -Cp)Fe(η 6 -arylhydrazine)] +

Carolina Manzur, Lorena Millán, MAURICIO DANIEL FUENTEALBA CARRASCO, Jean René Hamon, David Carrillo

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13 Scopus citations

Abstract

New mononuclear and dinuclear organometallic hydrazones [(η 5 - Cp)Fe(η 6 -R-C 6 H 4 NHN=CR'R'')]+PF 6 - , were synthesised by reacting the corresponding organometallic hydrazines [(η 5 -Cp)Fe(η 6 - RC 6 H 4 NHNH 2 )] + PF 6 - , with acetone, R=H, 2-Cl, 4-Me, 4-MeO; R'=R''=Me, and formylferrocene, R=H, 4-Me; R'=H; R''=(η 5 -C 5 H 4 )FeCp, respectively. (C) 2000 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)3615-3617
Number of pages3
JournalTetrahedron Letters
Volume41
Issue number19
DOIs
StatePublished - 6 May 2000

Keywords

  • Aromatic spacer
  • Ferrocenyl complexes
  • Homodinuclear complexes
  • Iron sandwich
  • Organometallic hydrazines
  • Organometallic hydrazones

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