TY - JOUR
T1 - Conversion of quinoline on ReS2 catalysts
T2 - Effect of the support and the addition of CS2 in the feed
AU - Bassi, Romina
AU - CamÚ, Esteban
AU - Villarroel, Mirza
AU - Javier Gil-LlambÍAs, F. C.O.
AU - GarcÍA-Fierro, J. L.
AU - Escalona, Néstor
AU - Baeza, Patricio
N1 - Funding Information:
The authors gratefully acknowledge Fondecyt Project N° 1130749 and 1140808, along with PFB-27 for financial support.
Publisher Copyright:
© 2017 Sociedad Chilena de Quimica. All Rights Reserved.
PY - 2017
Y1 - 2017
N2 - The effect of supports and the addition of CS2 in the feed were studied on hydrodenitrogenation of Quinoline in a continuous flow reactor over ReS2/support catalysts at 300, 325 and 350 °C and 3MPa of H2. The ReS2 supported on TiO2 displayed the highest activity followed by ZrO2, Al2O3 and SiO2 supports. The activity trend was correlated with the Re dispersion on the support. The effect of the addition of CS2 was increased activity until 2.5 v/v % content. At higher CS2 content the activity decreased due to competitive adsorption between CS2 and Quinoline on the active sites.
AB - The effect of supports and the addition of CS2 in the feed were studied on hydrodenitrogenation of Quinoline in a continuous flow reactor over ReS2/support catalysts at 300, 325 and 350 °C and 3MPa of H2. The ReS2 supported on TiO2 displayed the highest activity followed by ZrO2, Al2O3 and SiO2 supports. The activity trend was correlated with the Re dispersion on the support. The effect of the addition of CS2 was increased activity until 2.5 v/v % content. At higher CS2 content the activity decreased due to competitive adsorption between CS2 and Quinoline on the active sites.
KW - Carbon sulphide
KW - Quinoline
KW - Support
UR - http://www.scopus.com/inward/record.url?scp=85044735554&partnerID=8YFLogxK
U2 - 10.4067/s0717-97072017000403779
DO - 10.4067/s0717-97072017000403779
M3 - Article
AN - SCOPUS:85044735554
VL - 62
SP - 3779
EP - 3782
JO - Journal of the Chilean Chemical Society
JF - Journal of the Chilean Chemical Society
SN - 0717-9324
IS - 4
ER -