TY - JOUR
T1 - Facile synthesis of a luminescent copper(I) coordination polymer containing a flexible benzotriazole-based ligand
T2 - An effective catalyst for three-component azide-alkyne cycloaddition
AU - Nuñez-Dallos, Nelson
AU - Muñoz-Castro, Alvaro
AU - Fuentealba, Mauricio
AU - Pérez, Edwin G.
AU - Hurtado, John J.
N1 - Publisher Copyright:
© 2019 Elsevier B.V.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2019/12/1
Y1 - 2019/12/1
N2 - A straightforward method for the synthesis of a new luminescent copper(I) coordination polymer (CP) containing the ligand 1,3-bis(1H-benzotriazol-1-ylmethyl)benzene (L) through a self-assembly process with copper(I) iodide is reported. The CP was characterized by infrared, NMR, UV–Vis and photoluminescence spectroscopy, high resolution mass spectrometry (ESI), elemental and thermogravimetric analyses, single-crystal and powder X-ray diffraction, and relativistic density functional theory calculations. Furthermore, this one-dimensional copper(I) benzotriazole-based coordination polymer catalyzed the three-component azide-alkyne cycloaddition reaction to obtain 1,4-disubstituted 1,2,3-triazoles in good to excellent yields (up to 95%) from organic halides, sodium azide and terminal alkynes.
AB - A straightforward method for the synthesis of a new luminescent copper(I) coordination polymer (CP) containing the ligand 1,3-bis(1H-benzotriazol-1-ylmethyl)benzene (L) through a self-assembly process with copper(I) iodide is reported. The CP was characterized by infrared, NMR, UV–Vis and photoluminescence spectroscopy, high resolution mass spectrometry (ESI), elemental and thermogravimetric analyses, single-crystal and powder X-ray diffraction, and relativistic density functional theory calculations. Furthermore, this one-dimensional copper(I) benzotriazole-based coordination polymer catalyzed the three-component azide-alkyne cycloaddition reaction to obtain 1,4-disubstituted 1,2,3-triazoles in good to excellent yields (up to 95%) from organic halides, sodium azide and terminal alkynes.
KW - Azide-alkyne cycloaddition
KW - Catalysis
KW - Click chemistry
KW - Copper(I) coordination polymer
KW - Luminescence
UR - http://www.scopus.com/inward/record.url?scp=85072172853&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2019.119136
DO - 10.1016/j.ica.2019.119136
M3 - Article
AN - SCOPUS:85072172853
SN - 0020-1693
VL - 498
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
M1 - 119136
ER -