Molecular and Crystalline Structure of the Ruthenium(II) Complex [{trans-(dppe) 2 (Cl) Ru–C≡C–H} · 0.5CDCl 3 ]: An Additional Determination

C. A. Escobar, F. Madrid-Moliné, M. Fuentealba, J. C. Santos, P. Jara-Ulloa, A. Trujillo

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Abstract: The synthesis and X-ray diffraction study of the ruthenium(II) complex, [{trans-(dppe) 2 (Cl) Ru–C≡C–H} · 0.5CDCl 3 ] (trans-Ru · 0.5CDCl 3 ), are presented. The molecule of trans-Ru · 0.5CDCl 3 crystallizes in the triclinic sp. gr. P\1 with two chemically equivalent but crystallographic independent molecules. The intramolecular C–H···Cl–C hydrogen bonds build with the deuterated chloroform. In addition, the intermolecular C–H···Cl–Ru hydrogen bonds have been also found.

Original languageEnglish
Pages (from-to)1133-1137
Number of pages5
JournalCrystallography Reports
Issue number7
StatePublished - 1 Dec 2018
Externally publishedYes


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