Organometallic compounds containing the cis-[MoO(NNPhR)]2+ core (R = Me, Ph) - X-ray structures of [MoO(NNPh2)Me2(o-phen)] and [MoO(NNPh2)Ph2(o-phen)]

Ana M. Galindo; Macarena Mardones; Carolina Manzur; Daphne Boys; Jean René Hamon; David Carrillo

doi:10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u

Organometallic compounds containing the cis-[MoO(NNPhR)]²⁺ core (R = Me, Ph) - X-ray structures of [MoO(NNPh₂)Me₂(o-phen)] and [MoO(NNPh₂)Ph₂(o-phen)]

Ana M. Galindo, Macarena Mardones, Carolina Manzur, Daphne Boys, Jean René Hamon, David Carrillo

INSTITUTE OF CHEMISTRY

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Abstract

New organometallic compounds containing the cis-[MoO(NNPhR)]²⁺ core have been synthesized by means of a two-step procedure involving: (i) functionalization of the precursor [MoO₂Br₂(o-phen)] (1) with MePhNNH₂ and Ph₂NNH₂ to afford the intermediates [MoO(NNMePh)Br₂(o-phen)] (2) and [MoO(NNPh₂)Br₂(o-phen)] · MeCN (3), respectively, and (ii) reaction of these intermediates with Grignard reagents to give [MoO(NNPhR)Me₂(o-phen)] [R = Me (4), R = Ph (5)], [MoO(NNPhMe)Ph₂(o-phen)] (6), and [MoO(NNPh₂)Ph₂(o-phen)] · CH₂Cl₂ (7). These compounds have been characterized by ¹H-NMR, IR, and UV/Vis spectroscopy and the crystal and molecular structures of 5 and 7 have been determined by X-ray diffraction analysis.

Original language	English
Pages (from-to)	387-392
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Issue number	3
DOIs	https://doi.org/10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u
State	Published - 1999

Keywords

Hydrazido complexes
Molybdenum
Organometallic complexes
Phenanthroline
X-ray structure determination

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10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u

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Galindo, A. M., Mardones, M., Manzur, C., Boys, D., Hamon, J. R., & Carrillo, D. (1999). Organometallic compounds containing the cis-[MoO(NNPhR)]²⁺ core (R = Me, Ph) - X-ray structures of [MoO(NNPh₂)Me₂(o-phen)] and [MoO(NNPh₂)Ph₂(o-phen)]. European Journal of Inorganic Chemistry, (3), 387-392. https://doi.org/10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u

@article{56d964bac00e4b1ab09cfb8a28dafb5b,

title = "Organometallic compounds containing the cis-[MoO(NNPhR)]2+ core (R = Me, Ph) - X-ray structures of [MoO(NNPh2)Me2(o-phen)] and [MoO(NNPh2)Ph2(o-phen)]",

abstract = "New organometallic compounds containing the cis-[MoO(NNPhR)]2+ core have been synthesized by means of a two-step procedure involving: (i) functionalization of the precursor [MoO2Br2(o-phen)] (1) with MePhNNH2 and Ph2NNH2 to afford the intermediates [MoO(NNMePh)Br2(o-phen)] (2) and [MoO(NNPh2)Br2(o-phen)] · MeCN (3), respectively, and (ii) reaction of these intermediates with Grignard reagents to give [MoO(NNPhR)Me2(o-phen)] [R = Me (4), R = Ph (5)], [MoO(NNPhMe)Ph2(o-phen)] (6), and [MoO(NNPh2)Ph2(o-phen)] · CH2Cl2 (7). These compounds have been characterized by 1H-NMR, IR, and UV/Vis spectroscopy and the crystal and molecular structures of 5 and 7 have been determined by X-ray diffraction analysis.",

keywords = "Hydrazido complexes, Molybdenum, Organometallic complexes, Phenanthroline, X-ray structure determination",

author = "Galindo, {Ana M.} and Macarena Mardones and Carolina Manzur and Daphne Boys and Hamon, {Jean Ren{\'e}} and David Carrillo",

year = "1999",

doi = "10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u",

language = "English",

pages = "387--392",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "3",

}

Galindo, AM, Mardones, M, Manzur, C, Boys, D, Hamon, JR & Carrillo, D 1999, 'Organometallic compounds containing the cis-[MoO(NNPhR)]²⁺ core (R = Me, Ph) - X-ray structures of [MoO(NNPh₂)Me₂(o-phen)] and [MoO(NNPh₂)Ph₂(o-phen)]', European Journal of Inorganic Chemistry, no. 3, pp. 387-392. https://doi.org/10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u

TY - JOUR

T1 - Organometallic compounds containing the cis-[MoO(NNPhR)]2+ core (R = Me, Ph) - X-ray structures of [MoO(NNPh2)Me2(o-phen)] and [MoO(NNPh2)Ph2(o-phen)]

AU - Galindo, Ana M.

AU - Mardones, Macarena

AU - Manzur, Carolina

AU - Boys, Daphne

AU - Hamon, Jean René

AU - Carrillo, David

PY - 1999

Y1 - 1999

N2 - New organometallic compounds containing the cis-[MoO(NNPhR)]2+ core have been synthesized by means of a two-step procedure involving: (i) functionalization of the precursor [MoO2Br2(o-phen)] (1) with MePhNNH2 and Ph2NNH2 to afford the intermediates [MoO(NNMePh)Br2(o-phen)] (2) and [MoO(NNPh2)Br2(o-phen)] · MeCN (3), respectively, and (ii) reaction of these intermediates with Grignard reagents to give [MoO(NNPhR)Me2(o-phen)] [R = Me (4), R = Ph (5)], [MoO(NNPhMe)Ph2(o-phen)] (6), and [MoO(NNPh2)Ph2(o-phen)] · CH2Cl2 (7). These compounds have been characterized by 1H-NMR, IR, and UV/Vis spectroscopy and the crystal and molecular structures of 5 and 7 have been determined by X-ray diffraction analysis.

AB - New organometallic compounds containing the cis-[MoO(NNPhR)]2+ core have been synthesized by means of a two-step procedure involving: (i) functionalization of the precursor [MoO2Br2(o-phen)] (1) with MePhNNH2 and Ph2NNH2 to afford the intermediates [MoO(NNMePh)Br2(o-phen)] (2) and [MoO(NNPh2)Br2(o-phen)] · MeCN (3), respectively, and (ii) reaction of these intermediates with Grignard reagents to give [MoO(NNPhR)Me2(o-phen)] [R = Me (4), R = Ph (5)], [MoO(NNPhMe)Ph2(o-phen)] (6), and [MoO(NNPh2)Ph2(o-phen)] · CH2Cl2 (7). These compounds have been characterized by 1H-NMR, IR, and UV/Vis spectroscopy and the crystal and molecular structures of 5 and 7 have been determined by X-ray diffraction analysis.

KW - Hydrazido complexes

KW - Molybdenum

KW - Organometallic complexes

KW - Phenanthroline

KW - X-ray structure determination

UR - http://www.scopus.com/inward/record.url?scp=0032820548&partnerID=8YFLogxK

U2 - 10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u

DO - 10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u

M3 - Article

AN - SCOPUS:0032820548

SN - 1434-1948

SP - 387

EP - 392

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 3

ER -

Organometallic compounds containing the cis-[MoO(NNPhR)]²⁺ core (R = Me, Ph) - X-ray structures of [MoO(NNPh₂)Me₂(o-phen)] and [MoO(NNPh₂)Ph₂(o-phen)]

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