TY - JOUR
T1 - Organometallic compounds containing the cis-[MoO(NNPhR)]2+ core (R = Me, Ph) - X-ray structures of [MoO(NNPh2)Me2(o-phen)] and [MoO(NNPh2)Ph2(o-phen)]
AU - Galindo, Ana M.
AU - Mardones, Macarena
AU - Manzur, Carolina
AU - Boys, Daphne
AU - Hamon, Jean René
AU - Carrillo, David
PY - 1999
Y1 - 1999
N2 - New organometallic compounds containing the cis-[MoO(NNPhR)]2+ core have been synthesized by means of a two-step procedure involving: (i) functionalization of the precursor [MoO2Br2(o-phen)] (1) with MePhNNH2 and Ph2NNH2 to afford the intermediates [MoO(NNMePh)Br2(o-phen)] (2) and [MoO(NNPh2)Br2(o-phen)] · MeCN (3), respectively, and (ii) reaction of these intermediates with Grignard reagents to give [MoO(NNPhR)Me2(o-phen)] [R = Me (4), R = Ph (5)], [MoO(NNPhMe)Ph2(o-phen)] (6), and [MoO(NNPh2)Ph2(o-phen)] · CH2Cl2 (7). These compounds have been characterized by 1H-NMR, IR, and UV/Vis spectroscopy and the crystal and molecular structures of 5 and 7 have been determined by X-ray diffraction analysis.
AB - New organometallic compounds containing the cis-[MoO(NNPhR)]2+ core have been synthesized by means of a two-step procedure involving: (i) functionalization of the precursor [MoO2Br2(o-phen)] (1) with MePhNNH2 and Ph2NNH2 to afford the intermediates [MoO(NNMePh)Br2(o-phen)] (2) and [MoO(NNPh2)Br2(o-phen)] · MeCN (3), respectively, and (ii) reaction of these intermediates with Grignard reagents to give [MoO(NNPhR)Me2(o-phen)] [R = Me (4), R = Ph (5)], [MoO(NNPhMe)Ph2(o-phen)] (6), and [MoO(NNPh2)Ph2(o-phen)] · CH2Cl2 (7). These compounds have been characterized by 1H-NMR, IR, and UV/Vis spectroscopy and the crystal and molecular structures of 5 and 7 have been determined by X-ray diffraction analysis.
KW - Hydrazido complexes
KW - Molybdenum
KW - Organometallic complexes
KW - Phenanthroline
KW - X-ray structure determination
UR - http://www.scopus.com/inward/record.url?scp=0032820548&partnerID=8YFLogxK
U2 - 10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u
DO - 10.1002/(sici)1099-0682(199903)1999:3<387::aid-ejic387>3.0.co;2-u
M3 - Article
AN - SCOPUS:0032820548
SP - 387
EP - 392
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 3
ER -