TY - JOUR
T1 - Preparation and crystal structure of the new ionic bis-[hydrazido]-molybdenum complex [Mo(NNPh2)2(acac)(PPh3)2] +OTf-
AU - Manzur, Carolina
AU - Carrillo, David
AU - Baggio, Ricardo
AU - Garland, María Teresa
N1 - Funding Information:
The authors would like to thank Fundacion Andes for the purchase of the single crystal diffractometer currently operating at the Universidad de Chile. C.M. acknowledges financial support from Fondecyt grant 2920032.
PY - 1997/6
Y1 - 1997/6
N2 - The title compound [Mo(NNPh2)2(acac)(PPh3)2] +OTf-, Mr = 1233.1, crystallizes in the triclinic space group P1, with a = 12.881(4), b = 13.795(3), c = 17.160(5)Å, α = 90.95(1), β = 91.31(1), γ = 103.53(1)°, and Z = 2. The structure was solved by Patterson methods, and refined with some difficulties due to extensive disorder in the counterion. The Mo ion is hexacoordinated in an octahedral environment, with two O and two N defining the basal plane, and two P atoms in the apical sites.
AB - The title compound [Mo(NNPh2)2(acac)(PPh3)2] +OTf-, Mr = 1233.1, crystallizes in the triclinic space group P1, with a = 12.881(4), b = 13.795(3), c = 17.160(5)Å, α = 90.95(1), β = 91.31(1), γ = 103.53(1)°, and Z = 2. The structure was solved by Patterson methods, and refined with some difficulties due to extensive disorder in the counterion. The Mo ion is hexacoordinated in an octahedral environment, with two O and two N defining the basal plane, and two P atoms in the apical sites.
KW - Crystal structure
KW - Hydrazido-molybdenum complexes
KW - Molybdenum complexes
UR - http://www.scopus.com/inward/record.url?scp=0031530635&partnerID=8YFLogxK
U2 - 10.1007/BF02576565
DO - 10.1007/BF02576565
M3 - Article
AN - SCOPUS:0031530635
SN - 1074-1542
VL - 27
SP - 339
EP - 342
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 6
ER -