Preparation and crystal structure of the new ionic bis-[hydrazido]-molybdenum complex [Mo(NNPh2)2(acac)(PPh3)2] +OTf-

CECILIA CAROLINA MANZUR NAZAL, David Carrillo, Ricardo Baggio, María Teresa Garland

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

The title compound [Mo(NNPh2)2(acac)(PPh3)2] +OTf-, Mr = 1233.1, crystallizes in the triclinic space group P1, with a = 12.881(4), b = 13.795(3), c = 17.160(5)Å, α = 90.95(1), β = 91.31(1), γ = 103.53(1)°, and Z = 2. The structure was solved by Patterson methods, and refined with some difficulties due to extensive disorder in the counterion. The Mo ion is hexacoordinated in an octahedral environment, with two O and two N defining the basal plane, and two P atoms in the apical sites.

Original languageEnglish
Pages (from-to)339-342
Number of pages4
JournalJournal of Chemical Crystallography
Volume27
Issue number6
DOIs
StatePublished - Jun 1997

Keywords

  • Crystal structure
  • Hydrazido-molybdenum complexes
  • Molybdenum complexes

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