Reducing-effect of chloride for the dissolution of black copper

Oxidized black copper ores are known for their difficulty in dissolving their components of interest through conventional methods. This is due to its non-crystalline and amorphous structure. Among these minerals, copper pitch and copper wad are of great interest because of their considerable concentrations of copper and manganese. Currently, these minerals are not incorporated into the extraction circuits or left untreated, whether in stock, leach pads, or waste. For the recovery of its main elements of interest (Cu and Mn), it is necessary to use reducing agents that dissolve the present MnO₂, while allowing the recovery of Cu. In this research, the results for the dissolution of Mn and Cu from a black copper mineral are exposed, evaluating the reducing effect of NaCl for MnO₂ through pre-treatment of agglomerate and curing, and subsequently leaching in standard condition with the use of a reducing agent (Fe²⁺). High concentrations of chloride in the agglomerate process and prolonged curing times would favor the reduction of MnO₂, increasing the dissolution of Mn, while the addition of NaCl did not benefit Cu extractions. Under standard conditions, low Mn extractions were obtained, while in an acid-reducing medium, a significant dissolution of MnO₂ was achieved, which supports the removal of Cu.