SERS and theoretical studies of arginine

A. E. Aliaga; C. Garrido; P. Leyton; G. Diaz F.; J. S. Gomez-Jeria; T. Aguayo; E. Clavijo; M. M. Campos-Vallette; S. Sanchez-Cortes

doi:10.1016/j.saa.2010.01.007

SERS and theoretical studies of arginine

A. E. Aliaga, C. Garrido, P. Leyton, G. Diaz F., J. S. Gomez-Jeria, T. Aguayo, E. Clavijo, M. M. Campos-Vallette, S. Sanchez-Cortes

INSTITUTE OF CHEMISTRY

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61 Scopus citations

Abstract

Arginine amino acid (Arg) has been vibrationally studied through its infrared, Raman and surface-enhanced Raman scattering (SERS) spectra, and theoretical calculations. Net charge is used to predict the possibility to obtain the SERS spectrum of Arg in colloidal solution. The interpretation of the SERS spectral data suggests that the Arg-Ag nanoparticles interaction in a colloidal solution and in the case of the Arg coated by Ag is mainly verified through the guanidinium moiety. Theoretical calculations performed by using extended Hückel theory method for a model of Arg interacting with an Ag cluster support the observed SERS experimental result.

Original language	English
Pages (from-to)	458-463
Number of pages	6
Journal	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume	76
Issue number	5
DOIs	https://doi.org/10.1016/j.saa.2010.01.007
State	Published - 1 Sep 2010

Keywords

Ag cluster
Arginine
Raman spectrum
Surface-enhanced Raman scattering

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10.1016/j.saa.2010.01.007

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@article{5149b3422d97466abae06882a4854815,

title = "SERS and theoretical studies of arginine",

abstract = "Arginine amino acid (Arg) has been vibrationally studied through its infrared, Raman and surface-enhanced Raman scattering (SERS) spectra, and theoretical calculations. Net charge is used to predict the possibility to obtain the SERS spectrum of Arg in colloidal solution. The interpretation of the SERS spectral data suggests that the Arg-Ag nanoparticles interaction in a colloidal solution and in the case of the Arg coated by Ag is mainly verified through the guanidinium moiety. Theoretical calculations performed by using extended H{\"u}ckel theory method for a model of Arg interacting with an Ag cluster support the observed SERS experimental result.",

keywords = "Ag cluster, Arginine, Raman spectrum, Surface-enhanced Raman scattering",

author = "Aliaga, {A. E.} and C. Garrido and P. Leyton and {Diaz F.}, G. and Gomez-Jeria, {J. S.} and T. Aguayo and E. Clavijo and Campos-Vallette, {M. M.} and S. Sanchez-Cortes",

note = "Funding Information: This work was supported by the CSIC-CONICYT project 2007-145 and Fondecyt projects 1070078, 1085124 and 1090074, the Ministerio de Educaci{\'o}n y Ciencia of Spain project FIS2007-63065 and the Comunidad de Madrid project S-0505/TIC/0191 MICROSERES. AEA acknowledges project AT-24090050 CONICYT. GDF acknowledges project from the Universidad de Playa Ancha.",

year = "2010",

month = sep,

day = "1",

doi = "10.1016/j.saa.2010.01.007",

language = "English",

volume = "76",

pages = "458--463",

journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

issn = "1386-1425",

publisher = "Elsevier",

number = "5",

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TY - JOUR

T1 - SERS and theoretical studies of arginine

AU - Aliaga, A. E.

AU - Garrido, C.

AU - Leyton, P.

AU - Diaz F., G.

AU - Gomez-Jeria, J. S.

AU - Aguayo, T.

AU - Clavijo, E.

AU - Campos-Vallette, M. M.

AU - Sanchez-Cortes, S.

N1 - Funding Information: This work was supported by the CSIC-CONICYT project 2007-145 and Fondecyt projects 1070078, 1085124 and 1090074, the Ministerio de Educación y Ciencia of Spain project FIS2007-63065 and the Comunidad de Madrid project S-0505/TIC/0191 MICROSERES. AEA acknowledges project AT-24090050 CONICYT. GDF acknowledges project from the Universidad de Playa Ancha.

PY - 2010/9/1

Y1 - 2010/9/1

N2 - Arginine amino acid (Arg) has been vibrationally studied through its infrared, Raman and surface-enhanced Raman scattering (SERS) spectra, and theoretical calculations. Net charge is used to predict the possibility to obtain the SERS spectrum of Arg in colloidal solution. The interpretation of the SERS spectral data suggests that the Arg-Ag nanoparticles interaction in a colloidal solution and in the case of the Arg coated by Ag is mainly verified through the guanidinium moiety. Theoretical calculations performed by using extended Hückel theory method for a model of Arg interacting with an Ag cluster support the observed SERS experimental result.

AB - Arginine amino acid (Arg) has been vibrationally studied through its infrared, Raman and surface-enhanced Raman scattering (SERS) spectra, and theoretical calculations. Net charge is used to predict the possibility to obtain the SERS spectrum of Arg in colloidal solution. The interpretation of the SERS spectral data suggests that the Arg-Ag nanoparticles interaction in a colloidal solution and in the case of the Arg coated by Ag is mainly verified through the guanidinium moiety. Theoretical calculations performed by using extended Hückel theory method for a model of Arg interacting with an Ag cluster support the observed SERS experimental result.

KW - Ag cluster

KW - Arginine

KW - Raman spectrum

KW - Surface-enhanced Raman scattering

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U2 - 10.1016/j.saa.2010.01.007

DO - 10.1016/j.saa.2010.01.007

M3 - Article

C2 - 20471905

AN - SCOPUS:77953480467

SN - 1386-1425

VL - 76

SP - 458

EP - 463

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

IS - 5

ER -

SERS and theoretical studies of arginine

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Keywords

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