Surface enhanced vibrational (IR and Raman) spectroscopy in the design of chemosensors based on ester functionalized p-tert-butylcalix[4]arene hosts

P. Leyton; C. Domingo; S. Sanchez-Cortes; M. Campos-Vallette; J. V. Garcia-Ramos

doi:10.1021/la051761o

Surface enhanced vibrational (IR and Raman) spectroscopy in the design of chemosensors based on ester functionalized p-tert-butylcalix[4]arene hosts

P. Leyton, C. Domingo, S. Sanchez-Cortes, M. Campos-Vallette, J. V. Garcia-Ramos

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Surface-enhanced IR (SEIR) and Raman scattering (SERS) have been employed to study the adsorption of ester functionalized tert-butyl calix [4] arenes on Ag and Au nanostructured surfaces as well as their complexes with pyrene. The influence of adsorption and complexation with pyrene on the host calixarene structure was tested for two different calixarene molecules bearing carboethoxy groups (CH₃CH₂COOCH₂-) in the low rim at positions 1,3- and 1,2,3,4-, The results obtained with SEIR were compared to those obtained with SERS, to better understand the interaction mechanism of the studied calixarenes with the metallic surfaces and the ligand as well as to investigate the structure/selectivity relationship of these two surface techniques in the analysis of recognition problems in which these ester functionalized calixarene molecules are involved.

Original language	English
Pages (from-to)	11814-11820
Number of pages	7
Journal	Langmuir
Volume	21
Issue number	25
DOIs	https://doi.org/10.1021/la051761o
State	Published - 6 Dec 2005
Externally published	Yes

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abstract = "Surface-enhanced IR (SEIR) and Raman scattering (SERS) have been employed to study the adsorption of ester functionalized tert-butyl calix [4] arenes on Ag and Au nanostructured surfaces as well as their complexes with pyrene. The influence of adsorption and complexation with pyrene on the host calixarene structure was tested for two different calixarene molecules bearing carboethoxy groups (CH3CH2COOCH2-) in the low rim at positions 1,3- and 1,2,3,4-, The results obtained with SEIR were compared to those obtained with SERS, to better understand the interaction mechanism of the studied calixarenes with the metallic surfaces and the ligand as well as to investigate the structure/selectivity relationship of these two surface techniques in the analysis of recognition problems in which these ester functionalized calixarene molecules are involved.",

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T1 - Surface enhanced vibrational (IR and Raman) spectroscopy in the design of chemosensors based on ester functionalized p-tert-butylcalix[4]arene hosts

AU - Leyton, P.

AU - Domingo, C.

AU - Sanchez-Cortes, S.

AU - Campos-Vallette, M.

AU - Garcia-Ramos, J. V.

PY - 2005/12/6

Y1 - 2005/12/6

N2 - Surface-enhanced IR (SEIR) and Raman scattering (SERS) have been employed to study the adsorption of ester functionalized tert-butyl calix [4] arenes on Ag and Au nanostructured surfaces as well as their complexes with pyrene. The influence of adsorption and complexation with pyrene on the host calixarene structure was tested for two different calixarene molecules bearing carboethoxy groups (CH3CH2COOCH2-) in the low rim at positions 1,3- and 1,2,3,4-, The results obtained with SEIR were compared to those obtained with SERS, to better understand the interaction mechanism of the studied calixarenes with the metallic surfaces and the ligand as well as to investigate the structure/selectivity relationship of these two surface techniques in the analysis of recognition problems in which these ester functionalized calixarene molecules are involved.

AB - Surface-enhanced IR (SEIR) and Raman scattering (SERS) have been employed to study the adsorption of ester functionalized tert-butyl calix [4] arenes on Ag and Au nanostructured surfaces as well as their complexes with pyrene. The influence of adsorption and complexation with pyrene on the host calixarene structure was tested for two different calixarene molecules bearing carboethoxy groups (CH3CH2COOCH2-) in the low rim at positions 1,3- and 1,2,3,4-, The results obtained with SEIR were compared to those obtained with SERS, to better understand the interaction mechanism of the studied calixarenes with the metallic surfaces and the ligand as well as to investigate the structure/selectivity relationship of these two surface techniques in the analysis of recognition problems in which these ester functionalized calixarene molecules are involved.

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Surface enhanced vibrational (IR and Raman) spectroscopy in the design of chemosensors based on ester functionalized p-tert-butylcalix[4]arene hosts

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