Synthesis and characterization of alkoxycarbonylrhenium(III) complexes

A. Hugo Klahn; Carolina Manzur

doi:10.1016/S0277-5387(00)86886-2

Synthesis and characterization of alkoxycarbonylrhenium(III) complexes

A. Hugo Klahn, Carolina Manzur

INSTITUTE OF CHEMISTRY

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Abstract

The reaction of the cationic complexes [(η⁵-C₅Me₅)Re(CO)₃X]⁺ (X = Cl, Br and I) with alkoxide anions in alcohol or dichloromethane results in the formation of the alkoxycarbonylrhenium(III) complexes, trans-(η⁵-C₅Me₅)Re(CO)₂(I)(COOR) (X = Cl and Br, R = Me and X = I, R = Me, Et and i-Pr). The trans orientation of the carbonyl groups in these complexes was assigned by IR spectroscopy.

Original language	English
Pages (from-to)	1131-1134
Number of pages	4
Journal	Polyhedron
Volume	9
Issue number	9
DOIs	https://doi.org/10.1016/S0277-5387(00)86886-2
State	Published - 1990

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title = "Synthesis and characterization of alkoxycarbonylrhenium(III) complexes",

abstract = "The reaction of the cationic complexes [(η5-C5Me5)Re(CO)3X]+ (X = Cl, Br and I) with alkoxide anions in alcohol or dichloromethane results in the formation of the alkoxycarbonylrhenium(III) complexes, trans-(η5-C5Me5)Re(CO)2(I)(COOR) (X = Cl and Br, R = Me and X = I, R = Me, Et and i-Pr). The trans orientation of the carbonyl groups in these complexes was assigned by IR spectroscopy.",

author = "Klahn, {A. Hugo} and Carolina Manzur",

year = "1990",

doi = "10.1016/S0277-5387(00)86886-2",

language = "English",

volume = "9",

pages = "1131--1134",

journal = "Polyhedron",

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T1 - Synthesis and characterization of alkoxycarbonylrhenium(III) complexes

AU - Klahn, A. Hugo

AU - Manzur, Carolina

PY - 1990

Y1 - 1990

N2 - The reaction of the cationic complexes [(η5-C5Me5)Re(CO)3X]+ (X = Cl, Br and I) with alkoxide anions in alcohol or dichloromethane results in the formation of the alkoxycarbonylrhenium(III) complexes, trans-(η5-C5Me5)Re(CO)2(I)(COOR) (X = Cl and Br, R = Me and X = I, R = Me, Et and i-Pr). The trans orientation of the carbonyl groups in these complexes was assigned by IR spectroscopy.

AB - The reaction of the cationic complexes [(η5-C5Me5)Re(CO)3X]+ (X = Cl, Br and I) with alkoxide anions in alcohol or dichloromethane results in the formation of the alkoxycarbonylrhenium(III) complexes, trans-(η5-C5Me5)Re(CO)2(I)(COOR) (X = Cl and Br, R = Me and X = I, R = Me, Et and i-Pr). The trans orientation of the carbonyl groups in these complexes was assigned by IR spectroscopy.

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U2 - 10.1016/S0277-5387(00)86886-2

DO - 10.1016/S0277-5387(00)86886-2

M3 - Article

AN - SCOPUS:44949267056

SN - 0277-5387

VL - 9

SP - 1131

EP - 1134

JO - Polyhedron

JF - Polyhedron

IS - 9

ER -

Synthesis and characterization of alkoxycarbonylrhenium(III) complexes

Abstract

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