Thermodynamic Study of LiClO4 Activity Coefficients in Aqueous Solution at (288.15, 298.15, and 308.18) K

JAIME WILSON MORALES SAAVEDRA, CARLOS JAVIER CARLESI JARA, Héctor R. Galleguillos, Felipe Hernández-Luis, Raquel Rodríguez-Raposo

Research output: Contribution to journalArticlepeer-review


The use of various electrolyte materials in a lithium ion battery must be studied under stable electrochemical conditions; therefore, the LiClO4 activity coefficients in water at the temperatures described in this work are the result of an electrochemical cell (ISE): Na-ISE|LiClO4(m)|ClO4-ISE. For this study, the determination of activity coefficients was carried out using the Pitzer and Debye-Hückel equations to represent the relationship between log γ and molality. For the system used with the electrochemical cell, it has good the behavior of mean ionic activity coefficients of LiClO4 for all temperatures, and at a temperature of 298.15 K, there is good agreement between the experimental data and the data in the literature.

Original languageEnglish
Pages (from-to)3999-4004
Number of pages6
JournalJournal of Chemical and Engineering Data
Issue number11
StatePublished - 8 Nov 2018

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