TY - JOUR
T1 - Trans-Bis[1,2-bis(diphenylphosphanyl)ethane]chlorido(ethynyl)ruthenium(II)
AU - Trujillo, Alexander
AU - Fuentealba, Mauricio
AU - Arratia-Perez, Ramiro
AU - Howard, Judith A.K.
PY - 2012/12
Y1 - 2012/12
N2 - The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2] , consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The -C CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the -C CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions.
AB - The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2] , consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The -C CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the -C CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions.
KW - R factor = 0.030
KW - T = 120 K
KW - data-to-parameter ratio = 22.1
KW - disorder in main residue
KW - mean ω(C-C) = 0.003 Å
KW - single-crystal X-ray study
KW - wR factor = 0.072
UR - http://www.scopus.com/inward/record.url?scp=84870880846&partnerID=8YFLogxK
U2 - 10.1107/S1600536812044558
DO - 10.1107/S1600536812044558
M3 - Article
C2 - 23468677
AN - SCOPUS:84870880846
SN - 1600-5368
VL - 68
SP - m1445
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 12
ER -