Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source

S. A. Moya; C. Negrete-Vergara; K. Brown; V. Artigas; M. Fuentealba; V. Guerchais; P. Aguirre

doi:10.1016/j.catcom.2017.04.026

Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source

S. A. Moya, C. Negrete-Vergara, K. Brown, V. Artigas, M. Fuentealba, V. Guerchais, P. Aguirre

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Ruthenium complexes containing phosphorus-nitrogen, pincer-type (NPN) ligands show high activities and selectivities in the transfer hydrogenation of N-benzylideneaniline using propan-2-ol as the hydrogen source. Such is the case of complexes RuCl₂PPh₃(PPh(NHPy)₂) (1) and RuCl₂PPh₃(PPh(NHPyMe)₂) (2) which also show TOFs 5989 h^{− 1} and 5928 h^{− 1}, respectively. These remarkable results were obtained after only 10 min of reaction using a 1000/1 substrate/catalyst ratio.

Original language	English
Pages (from-to)	150-153
Number of pages	4
Journal	Catalysis Communications
Volume	99
DOIs	https://doi.org/10.1016/j.catcom.2017.04.026
State	Published - Aug 2017
Externally published	Yes

Keywords

Hydrogenation catalysis
Hydrogenation propan-2-ol
Ruthenium catalysts

Access to Document

10.1016/j.catcom.2017.04.026

Cite this

@article{e2d63145fdaf489e9f03d12145162964,

title = "Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source",

abstract = "Ruthenium complexes containing phosphorus-nitrogen, pincer-type (NPN) ligands show high activities and selectivities in the transfer hydrogenation of N-benzylideneaniline using propan-2-ol as the hydrogen source. Such is the case of complexes RuCl2PPh3(PPh(NHPy)2) (1) and RuCl2PPh3(PPh(NHPyMe)2) (2) which also show TOFs 5989 h− 1 and 5928 h− 1, respectively. These remarkable results were obtained after only 10 min of reaction using a 1000/1 substrate/catalyst ratio.",

keywords = "Hydrogenation catalysis, Hydrogenation propan-2-ol, Ruthenium catalysts",

author = "Moya, {S. A.} and C. Negrete-Vergara and K. Brown and V. Artigas and M. Fuentealba and V. Guerchais and P. Aguirre",

note = "Funding Information: This work has been supported by ECOS-CONICYT (Action C14E02). The authors acknowledge the financial support provided by Fondecyt-Chile (project 1160505) and the valuable comments of Sergio Alegr?a (USACh). This research has been performed as part of the Chilean-French ?Joint Laboratory for Inorganic Functional Materials? (LIAMIF N? 386). One of the authors (S.A.M.) thanks, Dicyt of the Universidad de Santiago de Chile. Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

month = aug,

doi = "10.1016/j.catcom.2017.04.026",

language = "English",

volume = "99",

pages = "150--153",

journal = "Catalysis Communications",

issn = "1566-7367",

}

Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source. / Moya, S. A.; Negrete-Vergara, C.; Brown, K.; Artigas, V.; Fuentealba, M.; Guerchais, V.; Aguirre, P.

In: Catalysis Communications, Vol. 99, 08.2017, p. 150-153.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source

AU - Moya, S. A.

AU - Negrete-Vergara, C.

AU - Brown, K.

AU - Artigas, V.

AU - Fuentealba, M.

AU - Guerchais, V.

AU - Aguirre, P.

N1 - Funding Information: This work has been supported by ECOS-CONICYT (Action C14E02). The authors acknowledge the financial support provided by Fondecyt-Chile (project 1160505) and the valuable comments of Sergio Alegr?a (USACh). This research has been performed as part of the Chilean-French ?Joint Laboratory for Inorganic Functional Materials? (LIAMIF N? 386). One of the authors (S.A.M.) thanks, Dicyt of the Universidad de Santiago de Chile. Publisher Copyright: © 2017 Elsevier B.V.

PY - 2017/8

Y1 - 2017/8

N2 - Ruthenium complexes containing phosphorus-nitrogen, pincer-type (NPN) ligands show high activities and selectivities in the transfer hydrogenation of N-benzylideneaniline using propan-2-ol as the hydrogen source. Such is the case of complexes RuCl2PPh3(PPh(NHPy)2) (1) and RuCl2PPh3(PPh(NHPyMe)2) (2) which also show TOFs 5989 h− 1 and 5928 h− 1, respectively. These remarkable results were obtained after only 10 min of reaction using a 1000/1 substrate/catalyst ratio.

AB - Ruthenium complexes containing phosphorus-nitrogen, pincer-type (NPN) ligands show high activities and selectivities in the transfer hydrogenation of N-benzylideneaniline using propan-2-ol as the hydrogen source. Such is the case of complexes RuCl2PPh3(PPh(NHPy)2) (1) and RuCl2PPh3(PPh(NHPyMe)2) (2) which also show TOFs 5989 h− 1 and 5928 h− 1, respectively. These remarkable results were obtained after only 10 min of reaction using a 1000/1 substrate/catalyst ratio.

KW - Hydrogenation catalysis

KW - Hydrogenation propan-2-ol

KW - Ruthenium catalysts

UR - http://www.scopus.com/inward/record.url?scp=85019911900&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2017.04.026

DO - 10.1016/j.catcom.2017.04.026

M3 - Article

AN - SCOPUS:85019911900

VL - 99

SP - 150

EP - 153

JO - Catalysis Communications

JF - Catalysis Communications

SN - 1566-7367

ER -

Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this