Pentamethylcyclopentadienyl organoiron(II) hydrazone complexes: Synthesis, spectroscopic characterization, and second-order nonlinear optical properties. X-ray crystal structure of [(η5 - C5 Me5) Fe (η6 - C6 H5) NHNH2] + PF6-

Mauricio Fuentealba, Loïc Toupet, Carolina Manzur, David Carrillo, Isabelle Ledoux-Rak, Jean René Hamon

Resultado de la investigación: Contribución a una revistaArtículorevisión exhaustiva

31 Citas (Scopus)

Resumen

A series of novel pentamethylated sandwich complexes based on the [Cp*Fe(η6-C6H5)]+ core (Cp* = η5-C5Me5) has been prepared. The new organometallic π-conjugated push-pull chromophores [Cp* Fe (η6 - C6 H5) -NHN {double bond, long} CHR] + PF6- (R = 2,4,6-Me3C6H2, 4; (η5-C5H5)Fe(η5-C5H4), 5) were prepared through condensations between the organometallic hydrazine precursor [Cp* Fe (η6 - C6 H5 NHNH2)] + PF6- (3), and either the mesitaldehyde or the ferrocenecarboxaldehyde, respectively. Their original design combines the cationic mixed sandwich acceptor (A) associated with an organic or organometallic donor (D) through the asymmetric hydrazone spacer -NH-N{double bond, long}CH-. The mesityl ring of 4 has been complexed by the arenophile Cp*Ru+, leading to the first η66-coordinated dinucleating hydrazone complex, {Mathematical expression} (6). Both the mono- and dinuclear hydrazones were stereoselectively obtained as their trans-isomers about the N{double bond, long}C double bond. All the new compounds were thoroughly characterized by a combination of elemental analysis and spectroscopic techniques (1H and 13C NMR, IR and UV-Vis). In addition, the solid-state structure of the organometallic hydrazine precursor 3 has been determined by X-ray diffraction study. Spectroscopic and electrochemical data of the organometallic hydrazones 4 and 5 clearly indicate a mutual donor-acceptor electronic influence resulting from conjugation between the end groups through the entire hydrazone backbone. Compounds 4 and 5 are strongly polarized D-π-A systems exhibiting low-lying intramolecular charge transfer bands in their electronic absorption spectra and enhanced second-order NLO properties (μβ), as measured by EFISH technique at 1.907 μm.

Idioma originalInglés
Páginas (desde-hasta)1099-1109
Número de páginas11
PublicaciónJournal of Organometallic Chemistry
Volumen692
N.º5
DOI
EstadoPublicada - 1 feb. 2007
Publicado de forma externa

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