Reaction between ferrocene-carboxaldehyde and dioxaphospholene: Characterization and crystal structures of an unexpected bisferrocenyldioxolane

Guillermo Ahumada, Thierry Roisnel, Carolina Manzur, David Carrillo, Jean René Hamon

Resultado de la investigación: Contribución a una revistaEstudio breverevisión exhaustiva

3 Citas (Scopus)

Resumen

Reacting an 1:1 stoichiometric molar ratio of ferrocenecarboxaldehyde and 2,2,2-trimethoxy-4,5-dimethyl-1,3,2-dioxaphospholene, neat, at room temperature for one week, leads to the diastereoselective formation of a bis-ferrocenyl 1,3-dioxolane complex 1-(4-methyl-2,5-diferrocenyl-1,3-dioxolan-4-yl)ethanone (1), in 30% isolated yield. The compound has been fully characterized by FT-IR, mono- and two-dimensional 1H and 13C NMR spectroscopy, elemental analysis, and cyclic voltammetry. Complex 1 has also been characterized by single crystal X-ray analysis.

Idioma originalInglés
Páginas (desde-hasta)40-44
Número de páginas5
PublicaciónJournal of Organometallic Chemistry
Volumen739
DOI
EstadoPublicada - 1 sept. 2013
Publicado de forma externa

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