Sedimentary records of organochlorine contaminants in Central Chilean Lakes

S. Focardi, R. Barra, K. Pozo, R. Urrutia, O. Parra, M. Cisternas, P. Pacheco

Resultado de la investigación: Capítulo del libro/informe/acta de congresoContribución a la conferenciarevisión exhaustiva

Resumen

Aquatic pollution by persistent organic compounds (POCs) in the southern hemisphere continues to be an important issue. Currently, no historic records of pollution are available to evaluate the inputs of chlorinated compounds and their environmental impact. Sedimentary records have been used to define the historical trend of pollution in lakes located in remote and urban areas. Sediment cores were collected from several urban and remote lakes in central Chile using a kayac sediment corer and cut into 1 cm slices. The organochlorine compounds were isolated in a soxhlet system with n-hexane, and successively identified and quantified by gas chromatography using an Electron Capture Detector (63 Ni). Principal Components Analysis (PCA) and Pearson correlation analysis were performed. The following pesticides were identified in the sediment cores: α-HCH, Lindane, Heptachlor, Aldrin, pp'-DDT, pp'-DDE and pp'-DDD. POC distributions and concentrations differed between pristine and urban lakes. In particular, pp'-DDE was present in every lake studied. Statistical analyses showed significant correlation between pp'-DDE and pp'-DDD in the urban lakes, while correlation between pp'-DDT and its metabolites were not detected. In addition, PCA showed compound clusters based on concentrations and degradation through time. Of all the study sites, Laguna Chica is the lake most polluted by POCs although concentrations are low compared to those reported for pristine areas.

Idioma originalInglés
Título de la publicación alojadaWater Pollution VI
Subtítulo de la publicación alojadaModelling Measuring and Prediction
EditoresR.A. Falconer, W.R. Blain, C.A. Brebbia
Páginas207-216
Número de páginas10
EstadoPublicada - 2001
Publicado de forma externa
EventoSixth International Conference on the Modelling, Monitoring and management of Water Pollution, Water Pollution VI - Rhodes, Grecia
Duración: 17 sep 200119 sep 2001

Serie de la publicación

NombreProgress in Water Resources

Conferencia

ConferenciaSixth International Conference on the Modelling, Monitoring and management of Water Pollution, Water Pollution VI
País/TerritorioGrecia
CiudadRhodes
Período17/09/0119/09/01

Huella

Profundice en los temas de investigación de 'Sedimentary records of organochlorine contaminants in Central Chilean Lakes'. En conjunto forman una huella única.

Citar esto