SERS study on the aggregation mechanisms resulting from the orientation of dipyridinic derivatives on gold nanoparticles

Rodrigo Sánchez-González, Viviana Silva, Constanza Suazo, Juan Pablo Soto, Santiago Sanchez-Cortes, Marcelo Campos-Vallette, Patricio Leyton, Elizabeth Imbarack

Resultado de la investigación: Contribución a una revistaArtículorevisión exhaustiva

2 Citas (Scopus)

Resumen

In this work, was studied the adsorption and orientation of three dipyridinic derivatives 9,10-bis-((E)-2-(pyridin-4-yl)vinyl)anthracene (DPAC), 1,4-bis-((E)-2-(pyridin-4-yl)vinyl)naphthalene (DPNA-T) and 2,6-bis-((E)-2-(pyridin-4-yl)vinyl)naphthalene (DPNA-L) on gold nanoparticles, using Surface Enhanced Raman Scattering (SERS). Systematic modification in the shapes of the bifunctional systems (Cross-shape, T-shape and Linear-shape) shows changes significant in the preferential orientation of these analytes on the nanostructured gold surface. Additional data from UV–vis measurements and TEM images are in agreement with the Reaction Limited Colloid Aggregation (RLCA) mechanisms for DPAC and DPNA-T and Diffusion Limited Colloid Aggregation (DLCA) mechanisms for DPNA-L, showing that for the same analyte concentration, the aggregation mechanism depends on the molecular shape. These results allow us to rationalize the fundamental aspects involved in the development of devices based on plasmonic resonance with potential applications in the field of molecular electronics.

Idioma originalInglés
Número de artículo120286
PublicaciónSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volumen264
DOI
EstadoPublicada - 5 ene. 2022
Publicado de forma externa

Huella

Profundice en los temas de investigación de 'SERS study on the aggregation mechanisms resulting from the orientation of dipyridinic derivatives on gold nanoparticles'. En conjunto forman una huella única.

Citar esto